Detalles del proyecto
Descripción
SiCf/SiCm composite materials are considered for accident tolerant fuel claddings for light water applications (LWR’s). The excellent neutronic properties, high strength and high temperature stability make them outstanding candidates. However, it was found that SiCf/SiCm composites do corrode in LWR conditions, which needs to be addressed before these promising cladding materials can be deployed. This program addresses this challenge utilizing a coating approach. We feature a high throughput screening approach to evaluate the best possible coating to protect the underlying SiCf/SiCm materials from LWR corrosion. The team aims to understand the interaction between the coating and the environment via corrosion testing and modeling but also investigates the interaction between substrate and coating with similar tools. Autoclave exposure of rapid screening coupons in prototypical environments in combination with thermodynamic modeling (CALPHAD) and Finite Element Methods (FEM) will be utilized. Special attention will be given to the coating/substrate mechanical bond since a debonding of the coating from the substrate is unacceptable. Small scale mechanical testing together with thermal cycling and FEM modeling will provide guidance on the ideal coating system design. Further, the team will incorporate the obtained knowledge into possible scalable technologies. The SiCf/SiCm manufacturer is engaged and we will investigate if the already well established Chemical Vapor Infiltration (CVI) technology can be adapted to allow coating in the same autoclave as the SiCf/SiCm manufacturing. The team recognizes the importance to provide a cost effective way in applying a protective coating on the SiCf/SiCm cladding tubes. The team aims to build upon already existing CVI infiltration capabilities to make a coating process scalable with little cost increase for the final component. Again, a fundamental understanding of the industrial coated SiCf/SiCm materials will be obtained allowing to make a through long term prediction of the coating in a reactor environment. Ultimately, one has to understand the materials performance under the combined corrosion and irradiation conditions. The team will utilize and adapt the already existing Irradiation and Corrosion tool at Los Alamos national Laboratory for LWR corrosion studies and aim to understand the effect of direct radiolysis on SiCf/SiCm as well as the coated SiCf/SiCm material.
Estado | Activo |
---|---|
Fecha de inicio/Fecha fin | 1/1/18 → … |
Enlaces | https://neup.inl.gov/SitePages/FY18_RandD_Awards.aspx |
Financiación
- Nuclear Energy University Program: USD800,000.00
!!!ASJC Scopus Subject Areas
- Superficies, recubrimientos y láminas
- Tecnología del combustible
- Energía nuclear e ingeniería